Some Theoretical Problems of Catalysis: Research ReportsTakao Kwan, Georgiĭ Konstantinovich Boreskov, Kenji Tamaru |
Contents
Preface | 3 |
Optimal Bond Energies with Catalyst of Reactants and Catalytic | 23 |
On the Activities of Oxide Catalysts for the Allylic Oxidation | 35 |
Copyright | |
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1-butene acetone acid acrolein activation energy adsorbed adsorption alkali metal allylic allylic oxidation atoms bond energy carbon monoxide catalyst catalyst surface catalytic activity catalytic groups catalytic reactions Chem chemical chemisorbed chemisorption complete oxidation concentration curve D₂ decrease dependence dioxide discharge stage electrode potential electrode surface electron transfer enzymatic reactions enzymes equation equilibrium ethylene exchange reaction experimental G. K. Boreskov H₂ H₂O HD formation heat heterogeneous catalysis hydrogen hydroxymercurated imidazole interaction intermediate isotopic k₁ kcal/mole kinetic Kinetika i Kataliz metal ion method molecular oxygen molecule N₂ nickel nitrogen observed obtained olefin overall reaction overvoltage oxidation of olefins oxidation of propylene oxide catalysts oxygen palladium partial oxidation platinum processes Professor properties proton rate constants reactant reaction rate redox redox decomposition reduced shown in Fig solution spectra step temperature tion transition metal u₁ unsaturated compound V₂ vanadium