Metal Ions in Biological Systems: Volume 31: Vanadium and its Role for LifeAstrid Sigel, Helmut Sigel "Volume 31, devoted solely to the role of vanadium in life processes, offers a comprehensive and timely account of this fascinating field by 37 distinguished, international authorities. Highlights the properties of the various oxidation states of vanadium, their affinity for biogenic ligands, the effects of vanadium species on enzyme activity, the role of vanadium in nitrogenases and haloperoxidases, and more." |
Contents
Redox Chemistry of Vanadium | 14 |
Chapter | 15 |
Coordination Compounds as Models for Biogenic | 20 |
Miscellaneous | 30 |
Chapter 2 | 32 |
SOLUTION PROPERTIES OF VANADIUMIII WITH | 45 |
Chapter 12 | 48 |
VanadiumIII in Ascidian Blood Cells | 74 |
Tunichrome Complexation and Redox Chemistry | 439 |
Ascidian Ecophysiology | 450 |
Outlook | 472 |
Chapter 14 | 491 |
Chemical Speciation of Vanadium in Living Organisms | 499 |
Physiological Roles of Vanadium | 505 |
VANADIUM TRANSPORT IN ANIMAL SYSTEMS | 511 |
Absorption | 518 |
Chapter 3 | 89 |
Structure Determination by EPR and ENDOR | 103 |
Application of Vanadyl as a Structural Probe of Biological | 120 |
Numbers in parentheses indicate the pages on which the authors | 129 |
Solid VanadylIVNucleotide Complexes | 137 |
Vanadates in Aqueous Solution | 150 |
Simple Complexes | 159 |
Chapter 6 | 211 |
Chapter 7 | 231 |
Chapter 8 | 249 |
Enzyme Activation by VanadiumIV | 272 |
Chapter 9 | 287 |
Chapter 10 | 325 |
Chapter 11 | 363 |
Outlook | 398 |
AMAVADIN THE VANADIUM COMPOUND | 407 |
Stereochemistry of the Organic Ligand | 413 |
Conclusion | 419 |
Plasma Transport | 526 |
Cellular Transport | 532 |
Chapter 16 | 543 |
Essentiality | 555 |
Assessment of Status | 561 |
Chapter 17 | 575 |
Acute Studies and Glucose Clamp Investigations | 585 |
ANTITUMOR ACTIVITY OF VANADIUM COMPOUNDS | 595 |
Conclusions and Perspectives | 610 |
N Dennis Chasteen Department of Chemistry University of | 617 |
Optical Spectroscopies | 634 |
51V Nuclear Magnetic Resonance Spectroscopy | 661 |
Sample Preparations | 674 |
| 689 | |
| 751 | |
| 767 | |
Common terms and phrases
51V NMR A. S. Tracey Acta activity algae amavadin amino acid analog aqueous solution ascidians atoms ATPase binding Biochem Biochemistry Biol Biological Systems Biophys blood cells carboxylate catalyze cation ceratodes Chem chemical chemistry cleavage compounds concentration coordination D. C. Crans decavanadate dimer divanadate dynein electron ENDOR enzyme equilibrium constants EXAFS FeMoco formation constant function H₂O hydrolysis imidazole inhibition inhibitor Inorg interaction kinase Kustin ligands lysates M. J. Gresser magnetic metal ions Mg2+ MoFe protein molecular molecules N. D. Chasteen N₂ nitrogen nitrogen fixation nitrogenase NMR spectroscopy nucleotides observed OH₂ oxidation oxygen paramagnetic peptide peroxidases peroxovanadate phosphatase phosphate phosphorylation photocleavage presence protein protons reaction redox reduction Rehder resonance species spectra spectroscopy spectrum structure studies substrate sulfate tion tunichrome tyrosine V(III vana vanadate vanadate esters vanadium vanadium(IV vanadyl Vilter VO2+ VO2+ ion
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