Metal Ions in Biological Systems: Volume 27: Electron Transfer Reactions in MetalloproteinsHelmut Sigel, Astrid Sigel Part of a series devoted to understanding the relationship between the chemistry of metals and life processes, the present volume offers contributions by 25 scientists covering mechanistic considerations, electron tunneling pathways, photoinduced and stereoselective effects in electron transfer reac |
Contents
THE ROLE OF DIVALENT METAL IONS IN PHOSPHORYL AND NUCLEOTIDYL | 2 |
Intermolecular Electron Transfer Reactions | 3 |
Chapter | 5 |
Chapter | 8 |
Intramolecular Electron Transfer across Polypeptides | 19 |
Electron Transfer Mediation via Polarizable Amino Acids | 32 |
ProteinSmall Molecule Electron Transfer Studies | 39 |
Comparison between Electron Transfer in Small Molecules | 47 |
Chapter 7 | 223 |
STEREOSELECTIVE EFFECTS IN ELECTRON TRANSFER REACTIONS | 265 |
General Discussion and Outlook | 283 |
Chapter 9 | 291 |
Other 2Fe2S Centers | 302 |
Binding Experiments | 313 |
Chapter 10 | 323 |
Theoretical Consideration of Mechanisms | 324 |
Chapter 2 | 57 |
David N Beratan Jet Propulsion Laboratory California Institute | 97 |
Chapter 3 | 98 |
Tunneling Pathways | 108 |
Future Directions | 121 |
DIPROTEIN COMPLEXES AND THEIR ELECTRON TRANSFER REACTIONS | 129 |
Cytochrome c and Cytochrome c Peroxidase | 135 |
Cytochrome c and Cytochrome b5 | 146 |
Cytochrome c and Plastocyanin | 154 |
FerredoxinNADP+ Reductase and Iron Proteins | 170 |
ELECTRON TRANSFER BETWEEN BOUND PROTEINS | 183 |
LONGRANGE ELECTRON TRANSFER IN CYTOCHROME C DERIVATIVES | 199 |
Intramolecular Electron Transfer | 209 |
Biochemical Isolation and Crystallization | 332 |
Conclusion | 352 |
Chapter 11 | 361 |
Electron Transfer Theory | 367 |
Photosynthetic Model Systems | 373 |
Concluding Remarks | 423 |
Chapter 12 | 431 |
Voltammetry of Redox Proteins at Carbon Electrodes | 447 |
Voltammetry of Redox Proteins at Gold Electrodes | 469 |
Reduction of Hydrogen Peroxide Catalyzed | 486 |
| 495 | |
| 521 | |
Common terms and phrases
A. G. Mauk A. G. Sykes Acta amino acid atoms B. M. Hoffman BChl binding Biochem Biochemistry Biol Biophys bridging ligands calculations Chem conformational copper proteins coupling covalent cytochrome Cytochrome b5 cytochrome c peroxidase dependence derivatives dielectric diprotein complex distance donor and acceptor donor-acceptor driving force dynamics elec electron transfer rate electron transfer reactions electron tunneling electrostatic enzyme factor ferredoxin flavin semiquinones flavodoxin free energy groups H. B. Gray heme hydrogen bonding Inorg interaction intracomplex intramolecular electron transfer ionic strength kinetic lysine mediation metalloprotein molecular molecules myoglobin orbitals oxidation peptides photosynthesis Phys plastocyanin porphyrin potential protein proton rate constant rate of electron rate of intramolecular reactants redox reduction reorganization energy residues Ru(His ruthenium S. S. Isied semiquinones solvent structure studies subunits superexchange surface temperature through-space tion Tollin tunneling matrix element tunneling pathways Ulstrup yeast
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