Metal Ions in Biological Systems: Volume 27: Electron Transfer Reactions in Metalloproteins

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Helmut Sigel, Astrid Sigel
CRC Press, Mar 15, 1991 - Science - 584 pages
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Part of a series devoted to understanding the relationship between the chemistry of metals and life processes, the present volume offers contributions by 25 scientists covering mechanistic considerations, electron tunneling pathways, photoinduced and stereoselective effects in electron transfer reac
 

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Contents

WANADIUM IN SELECTED BIOLOGICAL SYSTEMS
2
Intermolecular Electron Transfer Reactions
3
Chapter
5
Chapter
8
LITHIUM IN PSYCHIATRY
9
DETERMINATION OF LEAD CADMIUM AND MERCURY IN CLINICAL
10
INTESTINAL MAGNESIUM ABSORPTION
13
Intramolecular Electron Transfer across Polypeptides
19
ENDOR EPR and Electron Spin Echo for Probing
173
135
181
ELECTRON TRANSFER BETWEEN BOUND PROTEINS
183
LONGRANGE ELECTRON TRANSFER IN CYTOCHROME c DERIVATIVES
199
PHOTOINDUCED ELECTRON TRANSFER REACTIONS IN METALLOPROTEIN
223
COMPLEXES OF DCYCLOSERINE AND RELATED AMINO ACIDS WITH
262
STEREOSELECTIVE EFFECTS IN ELECTRON TRANSFER REACTIONS
265
INTERACTION OF METAL IONS WITH STREPTONIGRIN AND BIOLOGICAL
275

THE ROLE OF MAGNESIUM IN PREGNANCY FOR THE NEWBORN
25
Electron Transfer Mediation via Polarizable Amino Acids
32
ProteinSmall Molecule Electron Transfer Studies
39
CATION COMPLEXES OF THE MONOVALENT AND POLYWALENT CARBOXYLIC
46
Comparison between Electron Transfer in Small Molecules
47
CONCLUDING REMARKS
48
METALRESPONSIVE MOLECULAR
52
Chapter 2
57
ABBREVIATIONS
58
GENE FUNCTION AND REGULATION BY METAL
65
5
81
Chapter 3
97
STRUCTURE CATALYSIS AND SITEDIRECTED
113
DIPROTEIN COMPLEXES AND THEIR ELECTRON TRANSFER REACTIONS
129
Chapter 11
130
73
152
84
158
108
165
131
171
General Discussion and Outlook
283
Chapter 9
291
THE PROPERTIES OF BINUCLEAR COPPER CENTERS IN MODEL
297
Other 2Fe2S Centers
302
Binding Experiments 3 13
313
Chapter 10
323
Biochemical Isolation and Crystallization
332
MODELING THE PRIMARY ELECTRON TRANSFER EVENTS
361
METAL COMPLEXES AND THEIR BIOLOGICAL
400
Chapter 12
431
Out of print
439
IRONCONTAINING ANTIBIOTICS
457
184
495
146
497
157
503
187
515
191
521
174
533
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About the author (1991)

Helmut Sigel is Emeritus Professor (2003) of Inorganic Chemistry at the University of Basel, Switzerland, and a previous editor of the MIBS series until Volume 44. He serves on various editorial and advisory boards, published over 300 articles on metal ion complexes of nucleotides, coenzymes, and other ligands of biological relevance, and lectured worldwide. He was named Protagonist in Chemistry (2002) by ICA (issue 39); among further honours are the P. Ray Award (Indian Chemical Society, of which he is also an Honorary Fellow), the Werner Award (Swiss Chemical Society), a Doctor of Science honoris causa degree (Kalyani University, India), appointments as Visiting Professor (e.g. Austria, China, Japan, UK) and Endowed Lectureships.

Astrid Sigel has studied languages and was an editor for the Metal Ions in Biological Systems series (until Volume 44) and also of the Handbooks on Toxicity of Inorganic Compounds (1988), on Metals in Clinical and Analytical Chemistry (1944; both with H G Seiler), and on Metalloproteins (2001; with Ivano Bertini) (Dekker, New York).

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